Um no Luis.
In a fuel cell, you combine hydrogen with oxygen to produce water, heat (the reaction is exothermic), and energy. In the fuel cell you have an anode, cathode, and an electrolyte membrance. As hydrogen flows into the anode of the fuel cell, platinum coating on the anode helps to separate the gas into protons and electrons. The electrolyte membrane in the center allows only the protons to pass through the membrane to the cathode side of the fuel cell, where it reacts with the oxygen to form positively charged water. The electrons cannot pass through this membrane and flow through an external circuit to the positively charged water in the form of electric current.
This reaction occurs at about 80 degrees Celsius, or about 176 degrees Fahrenheit. A fuel cell produces about 0.7 volts, and can be chained together for a better effect.
Hydrogen is plentiful, but volatile. A spark will set off hydrogen provided there is oxygen. But think of it this way: Your gas tank also contains a pretty volatile substance. The difference is that one is a liquid and one a gas. More care is indeed needed to prevent an accident from happening. In the cars shown in Popular Science, the "gas" tank is air tight and when you fill up on hydrogen it actually compresses the air.
Or, companies use what is called a reformer. It will take certain gasses or liquids and extract hydrogen from it. Unfortunately, these reformers produce other gasses (pollution). If you could fill up on pure hydrogen, there would be no pollution (only water). But, if you use a reformer to extract hydrogen from say natural gas or methanol, you're going to have carbon as a byproduct, again.